High Quality Content by WIKIPEDIA articles! Atomic units (au or a.u.) form a system of natural units which is especially convenient for atomic physics calculations. There are two different kinds of atomic units, which one might name Hartree atomic units and Rydberg atomic units, which differ in the choice of the unit of mass and charge. This article deals with Hartree atomic units. In atomic units, the numerical values of the following four fundamental physical constants are all unity by definition: