High Quality Content by WIKIPEDIA articles! A glycogen branching enzyme is an enzyme which takes part in converting glucose to glycogen. It adds branches to the growing glycogen molecule. Glycogen is a branching polymer of large numbers of glucose units linked together. The structure is based on chains of glucose units with linkages between carbon atoms 1 and 4 of each pair of units. These linkages are catalyzed by the enzyme glycogen synthase.

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