High Quality Content by WIKIPEDIA articles! In physical organic chemistry, the Grunwald-Winstein equation is a linear free energy relationship between relative rate constants and the ionizing power of various solvent systems, describing the effect of solvent as nucleophile on different substrates. The equation, which was developed by Ernest Grunwald and Saul Winstein in 1948, could be written as equation 1.Where the kx, sol and kx, 80% EtOH are the solvolysis rate constants for a certain compound in different solvent systems and in the reference solvent, 80% aqueous ethanol, respectively. The m is a parameter of the compound measuring sensitivity of solvolysis rate to Y, the measure of ionizing power of the solvent.

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