High Quality Content by WIKIPEDIA articles! In chemistry, ligand close packing theory (LCP theory), sometimes called the ligand close packing model describes how ligand – ligand repulsions affect the geometry around a central atom. It has been developed by R.J Gillespie and others from 1997 onwards and is said to sit alongside VSEPR which was originally developed by R.J Gillespie and R Nyholm[3].The consistency of the interligand distances (F-F and O-F) in the above molecules is striking and this phenomenon is repeated across a wide range of molecules and forms the basis for LCP theory.

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