High Quality Content by WIKIPEDIA articles! The emergence of metallurgy in pre-Columbian Mesoamerica occurred relatively late in the region`s history, with distinctive works of metal apparent in West Mexico by roughly AD 800, and perhaps as early as AD 600. Metallurgical techniques likely diffused northward from regions in Central or South America via maritime trade routes; recipients of these metallurgical technologies apparently exploited a wide range of material, including alloys of copper-silver, copper-arsenic, copper-tin and copper-arsenic-tin.