Издательство: | Книга по требованию |
Дата выхода: | июль 2011 |
ISBN: | 978-6-1310-5206-4 |
Объём: | 76 страниц |
Масса: | 135 г |
Размеры(В x Ш x Т), см: | 23 x 16 x 1 |
High Quality Content by WIKIPEDIA articles! Niobium dioxide, is the chemical compound with the formula NbO2. It is a bluish black non-stoichiometric solid with a composition range of NbO1.94-NbO2.09. It can be prepared by reacting Nb2O5 with H2 at 800-1350 °C. An alternative method is reaction of Nb2O5 with Nb powder at 1100 °C. The room temperature form NbO2 has a tetragonal, rutile-like structure with short Nb-Nb distances indicating Nb-Nb bonding. High temp form also has a rutile-like structure with short Nb-Nb distances. Two high pressure phases have been reported one with a rutile-like structure, again with short Nb-Nb distances, and a higher pressure with baddeleyite-related structure.
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