Organobromine Compound

Organobromine Compound

Lambert M. Surhone, Miriam T. Timpledon, Susan F. Marseken

     

бумажная книга



Издательство: Книга по требованию
Дата выхода: июль 2011
ISBN: 978-6-1310-5357-3
Объём: 100 страниц
Масса: 172 г
Размеры(В x Ш x Т), см: 23 x 16 x 1

High Quality Content by WIKIPEDIA articles! Organobromine compounds are organic compounds that contain carbon bonded to bromine. The most pervasive is the naturally produced methyl bromide. One prominent application is the use of polybrominated diphenyl ethers as fire-retardants. A variety of minor organobromine compounds are found in nature, but none are biosynthesized or required by mammals. Organobromine compounds have fallen under increased scrutiny for their environmental impact. Most organobromine compounds, like most organohalide compounds, are relatively nonpolar. Bromine is more electronegative than carbon (2.8 vs 2.5). Consequently, the carbon in a carbon–bromine bond is electrophilic, i.e. alkyl bromides are alkylating agents. Carbon–halogen bond strengths, or bond dissociation energies are of 115, 83.7, 72.1, and 57.6 kcal/mol for bonded to fluorine, chlorine, bromine, or iodine, respectively. The reactivity of organobromine compounds resembles but is intermediate between the reactivity of organochlorine and organoiodine compounds.

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