Издательство: | Книга по требованию |
Дата выхода: | июль 2011 |
ISBN: | 978-6-1310-5370-2 |
Объём: | 120 страниц |
Масса: | 203 г |
Размеры(В x Ш x Т), см: | 23 x 16 x 1 |
High Quality Content by WIKIPEDIA articles! Organoiodine compounds are organic compound that contain one or more carbon–iodine bonds. They occur widely in organic chemistry, but are relatively rare in nature. The thyroxine hormones are organoiodine compounds that are required for health and the reason for government-mandated iodization of salt. The C–I bond is the weakest of the carbon–halogen bonds. These bond strengths correlate with the electronegativity of the halogen, decreasing in the order F > Cl > Br > I. This periodic order also follows the atomic radius of halogens and the length of the carbon-halogen bond. For example, in the molecules represented by CH3X, where X is a halide, the carbon-X bonds have strengths, or bond dissociation energies of 115, 83.7, 72.1, and 57.6 kcal/mol for X = fluoride, chloride, bromide, and iodide, respectively. Of the halides, iodide usually is the best leaving group. The other noteworthy aspect of organoiodine compounds is their high density, which arises from the high atomic weight of iodine. For example, one millilitre of methylene iodide weighs 3.325 g.
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