Oxidation of Secondary Alcohols to Ketones

Oxidation of Secondary Alcohols to Ketones

Lambert M. Surhone, Miriam T. Timpledon, Susan F. Marseken

     

бумажная книга



Издательство: Книга по требованию
Дата выхода: июль 2011
ISBN: 978-6-1310-5202-6
Объём: 88 страниц
Масса: 153 г
Размеры(В x Ш x Т), см: 23 x 16 x 1

High Quality Content by WIKIPEDIA articles! The oxidation of secondary alcohols to ketones is an important oxidation reaction in organic chemistry. When a secondary alcohol is oxidised, it is converted to a ketone. The hydrogen from the hydroxyl group is lost along with the hydrogen bonded to the second carbon. The remaining oxygen then double bonds with the carbon. This leaves a ketone, as R1-CO-R2. Ketones cannot normally be oxidised any further because this would involve breaking a C-C bond, which requires too much energy. The reaction can occur using a variety of oxidants. When a secondary alcohol is oxidised, it is converted to a ketone. The hydrogen from the hydroxyl group is lost along with the hydrogen bonded to the second carbon. The remaining oxygen then double bonds with the carbon. This leaves a ketone, as R1-CO-R2. Ketones cannot normally be oxidised any further because this would involve breaking a C-C bond, which requires too much energy. The reaction can occur using a variety of oxidants.

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