High Quality Content by WIKIPEDIA articles! The Pauli exclusion principle is a quantum mechanical principle formulated by Wolfgang Pauli in 1925. It states that no two identical fermions may occupy the same quantum state simultaneously. A more rigorous statement of this principle is that, for two identical fermions, the total wave function is anti-symmetric. For electrons in a single atom, it states that no two electrons can have the same four quantum numbers, that is, if n, l, and ml are the same, ms must be different such that the electrons have opposite spins.

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