High Quality Content by WIKIPEDIA articles! Racah's W-coefficients were introduced by Giulio Racah in 1942. These coefficients have a purely mathematical definition. In physics they are used in calculations involving the quantum mechanical description of angular momentum, for example in atomic theory. The coefficients appear when there are three sources of angular momentum in the problem. For example, consider an atom with one electron in an s orbital and one electron in a p orbital. Each electron has electron spin angular momentum and in addition the p orbital has orbital angular momentum (an s orbital has zero orbital angular momentum). The atom may be described by LS coupling or by jj coupling as explained in the article on angular momentum coupling. The transformation between the wave functions that correspond to these two couplings involves a Racah W-coefficient.

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