Издательство: | Книга по требованию |
Дата выхода: | июль 2011 |
ISBN: | 978-6-1347-3514-8 |
Объём: | 112 страниц |
Масса: | 190 г |
Размеры(В x Ш x Т), см: | 23 x 16 x 1 |
Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. Raney nickel is a solid catalyst composed of fine grains of a nickel-aluminium alloy, used in many industrial processes. It was developed in 1926 by American engineer Murray Raney as an alternative catalyst for the hydrogenation of vegetable oils in industrial processes. More recently it is used as a heterogeneous catalyst in a variety of organic syntheses, most commonly for hydrogenation reactions. Raney nickel is produced when a block of nickel-aluminium alloy is treated with concentrated sodium hydroxide. This treatment, called "activation", dissolves most of the aluminium out of the alloy. The porous structure left behind has a large surface area, which gives high catalytic activity. The ratio of nickel to aluminium is around 1 for the original material used by Raney, and may vary from about 1 to 4.
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