High Quality Content by WIKIPEDIA articles! Rhenium pentachloride is a compound of rhenium and chlorine. It is a red-brown solid that is very air sensitive and reacts with water to give hydrogen chloride. This compound was first discovered by Geilmann, Wrigge, and Biltz in 1933. Rhenium pentachloride was found to exist as a solid in the form of Re2Cl10, which has a bridged structure with octahedrally coordinated rhenium atoms and can be formulated Cl4Re(?-Cl)2ReCl4. It has a melting point of 220 °C and is a paramagnetic molecule. There has been no report of a boiling point for this compound. Rhenium pentachloride is a double hexagonally closed packed structure.

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