High Quality Content by WIKIPEDIA articles! The Simon-Glatzel equation is an empirical correlation describing the pressure dependence of the melting temperature. The pressure dependence of the melting temperature is small for small pressure changes because the volume change during fusion or melting is rather small. But very high pressures have a significant effect because the liquid has (normally) a larger volume than the solid and a higher pressure makes the melting thermodynamically unfavorable and leads therefore to a higher melting temperature. If the liquid has a smaller volume than the solid (as for ice and liquid water) a higher pressure leads to a lower melting point.

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