High Quality Content by WIKIPEDIA articles! Sodium silox is the name for an organosilicon compound that serves as a source of the siloxide anion [(CH3)3C]3SiO-. Complexes of this bulky anionic ligand often adopt with low coordination numbers. Examples include Ti(silox)3, Nb(silox)3(PMe3), and [Cr(silox)3]-. The sodium derivative, which has salt-like properties, is a cubane cluster. Related bulky anionic ligands include C5Me5-, (Me3Si)2N-, and NacNac-. Silox has a larger cone angle than C5Me5- and is a poorer donor. It is also larger than silylamides. For these reasons, silox anion forms highly unsaturated complexes.

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