High Quality Content by WIKIPEDIA articles! The square planar molecular geometry in chemistry describes the stereochemistry (spatial arrangement of atoms) that is adopted by certain chemical compounds. As the name suggests, molecules of this geometry have their atoms positioned at the corners of a square on the same plane about a central atom.The addition of two ligands to linear compounds, ML2, can afford square planar complexes. For example, [AuCl2]? adds chlorine to give square planar [AuCl4]?.

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