Standard Enthalpy Change of Neutralisation

Standard Enthalpy Change of Neutralisation

Lambert M. Surhone, Miriam T. Timpledon, Susan F. Marseken

     

бумажная книга



Издательство: Книга по требованию
Дата выхода: июль 2011
ISBN: 978-6-1310-7200-0
Объём: 88 страниц
Масса: 153 г
Размеры(В x Ш x Т), см: 23 x 16 x 1

High Quality Content by WIKIPEDIA articles! The standard enthalpy change of neutralisation is the change in enthalpy that occurs when an acid and base undergo a neutralisation reaction to form one mole of water under standard conditions (298 K and 1 atm), i.e. react to produce water and a salt. It is a special case of the standard enthalpy change of reaction. Equations for working out standard enthalpy of neutralisation: Q = mc?T Where: * Q is the heat energy liberated * m is the mass of the solution. * c is the specific heat capacity of the solution. * ?T is the temperature change of the reaction between an acid and a base. From this the standard enthalpy change (?H) can be calculated by dividing the negative of Q by the moles of the limiting reactant, usually moles of H+ ions. The standard enthalpy change of neutralisation for a strong acid and base is -57.3 kJ/mol. ?h=-q/n in kJmol-1 The standard enthalpy of mineral acids is far greater than that of organic acids. This is because strong acids ionise completely and yet organic acids ionise partially.

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