Издательство: | Книга по требованию |
Дата выхода: | июль 2011 |
ISBN: | 978-6-1310-5190-6 |
Объём: | 84 страниц |
Масса: | 147 г |
Размеры(В x Ш x Т), см: | 23 x 16 x 1 |
High Quality Content by WIKIPEDIA articles! Surflon S-111 (CAS 72968-3-88) is a commercial product consisting of perfluorinated carboxylic acids (PFCAs) in ammonium salt form. It is commonly used as a polymerization aid in the production of fluoropolymers. The dominant chemical compound is perfluorononanoic acid (PFNA) at 74% by weight, followed by the 11 carbon perfluoroundecanoic acid (20%), and the 13 carbon perfluorotridecanoic acid (5%). Surflon S-111 is synthesized in Japan by oxidizing a mixture of fluorotelomer olefins. Fluorotelomer olefins are synthesized using a telomerization of tetrafluoroethylene taxogens (monomers), followed by an ethylene insertion.The olefin is oxidized, removing one carbon to yield products with an odd number of carbons with even-lengthed fluorocarbon chains plus a carboxylic acid group. As the fluorotelomer olefins are dominated by F(CF2)8CH=CH2,PFNA is the major PFCA product. Surflon S-111 "is described as Fatty acids, C7-C13, perfluoro, ammonium salts" and contains minor levels of other length PFCAs such as perfluorooctanoic acid (PFOA).
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