Thermodynamic versus kinetic reaction control

Thermodynamic versus kinetic reaction control

Jesse Russell Ronald Cohn

     

бумажная книга



ISBN: 978-5-5145-3181-3

High Quality Content by WIKIPEDIA articles! Thermodynamic reaction control or kinetic reaction control in a chemical reaction can decide the composition in a reaction product mixture when competing pathways lead to different products and the reaction conditions influence the selectivity. The distinction is relevant when product A forms faster than product B because the activation energy for product A is lower than that for product B, yet product B is more stable. In such a case A is the kinetic product and is favoured under kinetic control and B is the thermodynamic product and is favoured under thermodynamic control.